Lecture 9 Fossil Technologies

Gang He

September 28, 2023

Sample analytic questions

  • How much coal can be saved/emissions can be mitigated if China’s average coal power efficiency increased by 1 percentage point?
  • Why combined heat and power saves energy?

Thermodynamics

  • Thermodynamic efficiency
  • Comparing different technologies
  • Thermodynamics provides physic limits

Heat engine

Heat -> Mechanical energy (work)

Laws of thermodynamics

  • Zeroth law
    “If two systems are each in thermal equilibrium with a third, they are also in thermal equilibrium with each other.”

  • First law
    “In a process without transfer of matter, the change in internal energy, \(\Delta U\), of a thermodynamic system is equal to the energy gained as heat, \(Q\), less the thermodynamic work, \(W\), done by the system on its surroundings.”

  • Second law
    “Heat does not spontaneously flow from a colder body to a hotter body.”

  • Third law
    “As the temperature of a system approaches absolute zero, all processes cease and the entropy of the system approaches a minimum value.”

Three efficiencies

  • 1st law: actual, thermal efficiency;
    \(\eta_1 =\frac{W_{net}}{Q_{in}}=\frac{Q_{high}-Q_{low}}{Q_{high}}=1-\frac{Q_{low}}{Q_{high}}\)
  • Carnot: maximum possible efficiency;
    \(\eta_c =\frac{W_{net}}{Q_{high}}=\frac{T_{high}-T_{low}}{T_{high}}=1-\frac{T_{low}}{T_{high}}\) (Kelvin)
  • 2nd law: comparing 1st and Carnot;
    \(\eta_2 =\frac{\eta_1}{\eta_c}\)

A gas turbine engine

A steam coal plant

Brayton cycle vs. Rankine cycle

Jet engine, gas turbine

Steam engine, steam turbine

Brayton cycle vs. Rankine cycle

Brayton Cycle Rankine Cycle
Jet, Gas turbine Steam turbine
Open Open/closed circuits
Working fluid in gaseous phase Working fluid phase change

Largest coal plant in the U.S.

Georgia Power plant Scherer (3,720 MW)

Can you identify the components

  • Coal storage
  • Generating unit
  • Cooling stack
  • Bottom ash landfill
  • Sub-station
  • Transimission lines
  • Waste/pollution management

Combined cycle

CCGT Diagram

Defining a Rosenfeld Plant

  • 500 MW
  • c.f.: 70%
  • T&D losss: 7%

Results:

  • 3 TWh/year

  • 3 MtCO2/year

  • NYC electricity use: ~4 TWh/year

References

Koomey, Jonathan, Hashem Akbari, Carl Blumstein, Marilyn Brown, Richard Brown, Chris Calwell, Sheryl Carter, et al. 2010. “Defining a Standard Metric for Electricity Savings.” Environmental Research Letters 5 (1): 014017. https://iopscience.iop.org/article/10.1088/1748-9326/5/1/014017.